Jul 09, 2025

How does an ozone sensor work?

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Ozone, a molecule composed of three oxygen atoms (O₃), plays a dual - role in our environment. In the stratosphere, it forms a protective layer shielding the Earth from harmful ultraviolet radiation. However, at ground - level, ozone is a pollutant with adverse effects on human health and the environment. Given its importance, accurately detecting ozone levels is crucial. As a leading ozone sensor supplier, I'm excited to delve into how an ozone sensor works.

The Basics of Ozone Detection

Before we explore the working mechanism, it's essential to understand the need for ozone sensors. In industrial settings, ozone can be a by - product of various processes such as water purification, air disinfection, and semiconductor manufacturing. In environmental monitoring, measuring ground - level ozone helps in assessing air quality.

There are several types of ozone sensors available in the market, each with its own unique working principle. The most common ones include electrochemical sensors, semiconductor sensors, and ultraviolet (UV) absorption sensors.

Electrochemical Ozone Sensors

Electrochemical sensors are widely used for ozone detection due to their high sensitivity, selectivity, and relatively low cost. These sensors operate based on the principle of electro - chemical reactions.

An electrochemical ozone sensor typically consists of three main components: a working electrode, a counter electrode, and a reference electrode, all immersed in an electrolyte solution. When ozone comes into contact with the working electrode, an oxidation or reduction reaction occurs.

For example, in an ozone sensor, ozone molecules react with the working electrode surface. Ozone is a strong oxidizing agent, and it can accept electrons from the electrode. The reaction can be represented as follows:
O₃ + 2H⁺+ 2e⁻→ O₂ + H₂O

This reaction generates an electric current that is proportional to the concentration of ozone in the gas sample. The counter electrode serves to balance the electrochemical reaction, while the reference electrode provides a stable potential against which the working electrode's potential is measured.

The sensor electronics then amplify and convert this current into a voltage signal, which can be further processed and displayed as an ozone concentration reading. Electrochemical sensors are known for their fast response times and can detect ozone concentrations in the parts - per - billion (ppb) range.

Semiconductor Ozone Sensors

Semiconductor sensors offer another approach to ozone detection. These sensors are based on the change in the electrical conductivity of a semiconductor material when it interacts with ozone.

A typical semiconductor ozone sensor is made of a metal oxide semiconductor, such as tin oxide (SnO₂) or zinc oxide (ZnO). In the absence of ozone, the semiconductor material has a certain base conductivity due to the presence of free electrons and holes.

When ozone comes into contact with the semiconductor surface, it adsorbs onto the surface and reacts with the adsorbed oxygen ions and the semiconductor material. Ozone, being a strong oxidizing agent, can extract electrons from the semiconductor. This leads to a decrease in the number of free electrons in the semiconductor, resulting in an increase in its electrical resistance.

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The change in resistance is measured by passing a small current through the semiconductor material and measuring the voltage across it. The relationship between the change in resistance and the ozone concentration is calibrated during the manufacturing process.

Semiconductor sensors are relatively inexpensive, robust, and have a long lifespan. They are suitable for applications where a wide range of ozone concentrations need to be detected. If you are interested in a high - quality semiconductor ozone sensor, you can check out our Semiconductor Ozone Gas Sensor SMT - 038.

Ultraviolet (UV) Absorption Ozone Sensors

UV absorption sensors operate on the principle that ozone absorbs ultraviolet light at specific wavelengths. The most commonly used wavelength for ozone detection is around 254 nm.

A UV absorption ozone sensor consists of a UV light source, a sample cell, and a UV detector. The UV light is passed through the sample cell, which contains the gas sample to be analyzed. If ozone is present in the sample, it absorbs a portion of the UV light.

The amount of light absorbed is proportional to the concentration of ozone in the gas sample, according to the Beer - Lambert law. The detector measures the intensity of the transmitted light. By comparing the intensity of the transmitted light with the intensity of the incident light, the ozone concentration can be calculated.

UV absorption sensors are highly accurate and can provide real - time measurements. They are often used in high - precision applications such as environmental research and calibration of other ozone sensors. However, they are relatively expensive and require regular maintenance to ensure accurate operation.

Calibration and Maintenance of Ozone Sensors

Regardless of the type of ozone sensor, calibration is a critical step to ensure accurate and reliable measurements. Calibration involves exposing the sensor to known concentrations of ozone and adjusting the sensor's output to match these known values.

For electrochemical sensors, calibration is typically done using gas mixtures with known ozone concentrations. The sensor's response is adjusted by changing the gain and offset of the sensor electronics. Semiconductor sensors also require calibration to account for variations in the manufacturing process and environmental factors.

Maintenance of ozone sensors is also important for their long - term performance. Electrochemical sensors need to be protected from contaminants and extreme temperatures. The electrolyte in electrochemical sensors may dry out over time, and it may need to be replaced periodically.

Semiconductor sensors should be kept clean to prevent the buildup of dust and other contaminants on the sensor surface, which can affect the sensor's response. UV absorption sensors require regular cleaning of the UV light source and the detector to maintain their sensitivity.

Applications of Ozone Sensors

Ozone sensors have a wide range of applications. In the environmental monitoring field, they are used to measure ground - level ozone concentrations in urban areas, industrial zones, and near power plants. This data helps in assessing air quality and implementing pollution control measures.

In the industrial sector, ozone sensors are used in water treatment plants to monitor the ozone levels during the disinfection process. In semiconductor manufacturing, ozone sensors are used to ensure a clean and controlled environment, as ozone can affect the quality of semiconductor products.

In indoor air quality monitoring, ozone sensors can detect the presence of ozone generated by air purifiers, photocopiers, and other office equipment. This helps in maintaining a healthy indoor environment for occupants.

Conclusion

As an ozone sensor supplier, we understand the importance of providing high - quality sensors that can accurately detect ozone levels. Whether you need a sensor for environmental monitoring, industrial applications, or indoor air quality control, we have a range of options to meet your needs.

The working principles of ozone sensors, whether electrochemical, semiconductor, or UV absorption, are based on well - established scientific concepts. Each type of sensor has its own advantages and disadvantages, and the choice of sensor depends on the specific application requirements.

If you are interested in purchasing ozone sensors or have any questions about ozone detection, please feel free to contact us. We are ready to discuss your needs and provide you with the best solutions for your ozone sensing applications.

References

  1. K. N. Plessy, "Ozone Measurement Techniques", Journal of Atmospheric and Oceanic Technology, Vol. 11, pp. 1142 - 1154, 1994.
  2. S. R. Springston, "Electrochemical Gas Sensors: Principles and Applications", Sensors and Actuators B: Chemical, Vol. 44, pp. 403 - 412, 1997.
  3. M. A. Rahman, "Semiconductor Gas Sensors: Principles and Applications", Sensors and Actuators B: Chemical, Vol. 118, pp. 1 - 20, 2006.
  4. D. J. Seidel, "UV Absorption Ozone Sensors: Theory and Practice", Journal of Environmental Monitoring, Vol. 5, pp. 381 - 386, 2003.
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